BASIC 

PRINCIPLES

THE SILVER/SILVER CHLORIDE ELECTRODE

The silver/silver chloride electrode is a reference electrode of the second kind where the metal (silver) is in contact with a slightly soluble salt (silver chloride) containing the metal, which in turn is in contact with a solution containing the common anion (chloride ion). The ions in the solid phase and those in the liquid phase are in equilibrium. 

 

Silver/silver chloride electrodes have been used extensively in laboratories as internal reference electrodes, for example pH devices, because of their stability and accuracy. They have been used for many years in conventional cathodic protection particularly marine environments where copper electrodes are easily contaminated by the salt (NaCl) content. Recent developments in production techniques now enable robust silver/silver chloride electrodes to also be used as portable or permanently installed electrodes to measure the potential of steel in concrete and soil environments, for example steel re-bar in concrete and buried steel pipelines.

 

Silver/silver chloride electrodes utilise the reversible relationship as shown below:

As with any electrode of this type the potential difference between each, and the standard hydrogen electrode under standard conditions of temperature and pressure, has been precisely measured in a laboratory. The change in potential due to variations in the temperature and anions, which would be the chloride ions in the case of the silver/silver chloride can be theoretically calculated using the Nernst Equation. 

 

 

 

 

 

 

 

 

 

Silvion reference electrodes are developed in-house and are manufactured using a "unique” and advanced technique which results in a porous silver matrix. This porous matrix increases the active area of the monitoring surface and enables the deposition of a larger quantity of silver chloride. The deposition is precisely controlled by electrolytic coating and provides high reliability, high stability, greater accuracy and increased life performance. Silvion electrodes consist of an acetal housing body, and a porous ceramic disc at one end of the assembly allows contact between the field environment and the silver chloride electrode via the electrolyte. These discs are specially designed to reduce drying out problems and to insure low contact resistance to earth, providing more reliable readings. An insulated lead wire connects the central silver wire which can be connected to a high input impedance voltmeter (10MOhm) when measuring the voltage potential of structures to be protected. For embedding in concrete or for use in soil or potable water, the reference electrode contains potassium chloride (KCl) to stabilise the silver chloride concentration.


 

 
Potential relationships for several different reference electrodes

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Registered Office: Windsor House, A1 Business Park at Long Bennington, Nottinghamshire NG23 5JR